Lec 4 | MIT 5.80 Small-Molecule Spectroscopy and Dynamics, Fall 2008 Video Lecture, MIT

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Small Molecule Spectroscopy and Dynamics

Lecture 5: | MIT 5.80 Small-Molecule Spectroscopy and Dynamics, Fall 2008

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Lecture Details :

Lecture 4: Atoms: 1e- and alkali

Instructor: Robert Field

http://ocw.mit.edu/5-80F08

License: Creative Commons BY-NC-SA
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Course Description :

The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbation theory (van Vleck transformation); qualitative molecular orbital theory (Walsh diagrams); the notation of atomic and molecular spectroscopy.

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