Thermodynamics and Kinetics

MIT , Prof.Moungi Bawendi Keith Nelson

Colligative Properties

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Course Description

State of a system, 0th Law, Equation of State – Work, heat, first law – Internal energy, expansion work – Enthalpy-Adiabatic Changes – Thermochemistry-Calorimetry-Second Law – Entropy and the Clausius Inequality – Fundamental equation, Absolute S, Third Law – Criteria for Spontaneous Change – Gibbs Free Energy – Multicomponent Systems, Chemical Potential -Chemical Equilibrium – Temperature, Pressure, and Kp – Equilibrium: Application to Drug Design – Phase Equilibria – One Component – Clausius – Clapeyron Equation – Phase Equilibria – Two Components

Ideal Solutions – Non-ideal Solutions – Colligative PropertiesIntroduction to Statistical Mechanics – Partition Function (q) – Large N limit – Statistical Mechanics and discrete energy levels – Model Systems – Applications: Chemical and Phase Equilibria -Introduction to Reaction Kinetics – Complex Reactions and Mechanisms – Steady-state Equilibrium Approximations – Chain Reactions – Temperature Dependence, Ea, Catalysis – Enzyme Catalysis – Autocatalysis and Oscillators

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