Small Molecule Spectroscopy and Dynamics

MIT Course , Fall 2008 , Prof. Robert Field

148 students enrolled

Overview

The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbation theory (van Vleck transformation); qualitative molecular orbital theory (Walsh diagrams); the notation of atomic and molecular spectroscopy.

Lecture 14:

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        Lecture Details

        Lecture 13 Laser schemes for rotational assignment first lines for Ω, Ω" assignments Instructor Robert Field httpocw.mit.edu5-80F08 License Creative Commons BY-NC-SA More information at httpocw.mit.eduterms More courses at httpocw.mit.edu

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