# Small Molecule Spectroscopy and Dynamics

MIT,, Fall 2008 , Prof. Robert Field

Updated On 02 Feb, 19

MIT,, Fall 2008 , Prof. Robert Field

Updated On 02 Feb, 19

The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbation theory (van Vleck transformation); qualitative molecular orbital theory (Walsh diagrams); the notation of atomic and molecular spectroscopy.

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Lecture 19 Second-order effects

Instructor Robert Field

License Creative Commons BY-NC-SA

More information at httpocw.mit.eduterms

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Sam

Sep 12, 2018

Excellent course helped me understand topic that i couldn't while attendinfg my college.

Dembe

March 29, 2019

Great course. Thank you very much.