Introductory Quantum Mechanics

MIT Course , Spring 2004 , Prof. Robert Field

77 students enrolled

Overview

Introduction to the Spectroscopic Effective Hamiltonian - Spectroscopic Pertubations, Predissociation, and Autoionization - Semiclassical Methods for Calculating Vibrational Overlap Integrals - Wavepackets and Landau-Zener

Lecture 3: Semiclassical Methods for Calculating Vibrational Overlap Integrals

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        Lecture Details

        All coupling processes are mediated by vibrational overlap integrals, which are computed numerically. Semiclassical calculation of overlaps reveals physical factors controlling computed values the length of the stationary phase region is controlled by the slopes of the potential curves at the intersection and the velocity in the crossing region.

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