Introduction and Review – Need for Analysis Additional Thermodynamic Functions State and Path Variables – Equations for a Closed system Chemical Potential Concept Gibbs-Duhem Equation – Maxwell’s relations – Inter-Relationships between Thermodynamic Variables – Some Useful Mathematical Manipulations – Thermodynamic Relations for a Closed System with 1 mole of a pure Substances – Maximum Work,Lost Work Review of Closed Systems – Open Systems – Equations of State – Virial Equations – Equations of State – Cubic Equations – Volume Estimation – Generalized correlations – Residual Properties – Residual Properties – Generalized Correlations and Residual Properties – Fugacity Coefficient Estimation – Learning Aspects Chemical Potential Formulations – Lewis and Randall rule partial Molar Properties – Partial Molar Property Estimation from Mixing Experiments – Excess Property – Activity Coefficient from Excess Property – Models for Activity Coefficient in Binary System – Models for Activity Coefficient in Binary Systems – Criteria for Phase Equilibrium Phase Rule for Non-reacting Biosystems – Clausius – Clayperon Equation – Clausius – Clayperon Equation(cont.,)vapour-Liquid Equilibrium – Vapour-Liquid Equilibrium.Estimation of Fugacity coefficient – Liquid/Liquid and Solid/Liquid Equilibria – Criteria for Bio-reaction Equilibria – Phase rule for Reacting Biosystems Equilibrium constants – Effect of Temperature and Pressure on the Equilibrium constants – Reaction in Liquid or Solid Phases – Free energy Changes for some Bioreactions – Electrolytes – Course Review

Other Resources

Course Curriculum

Introduction and Review Details 46:55
Need for Analysis Additional Thermodynamic Functions State and Path Variables Details 49:6
Equations for a Closed system Chemical Potential Concept Gibbs-Duhem Equation Details 43:26
Maxwell’s relations Details 48:50
Inter-Relationships between Thermodynamic Variables Details 49:43
Some Useful Mathematical Manipulations Details 49:58
Thermodynamic Relations for a Closed System with 1 mole of a pure Substances Details 49:43
Maximum Work,Lost Work Review of Closed Systems Details 45:42
Open Systems Details 50:25
Equations of State – Virial Equations Details 50:30
Equations of State – Cubic Equations Details 50:17
Volume Estimation Details 48:15
Volume Estimation (cont.,)Generalized correlations Details 49:17
Generalized correlations(cont)Residual Properties Details 49:54
Residual Properties(cont.,) Details 50:13
Generalized Correlations and Residual Properties Details 48:54
Fugacity Coefficient Estimation Details 50:38
Review of Module 3 Details 0:43
Learning Aspects Chemical Potential Formulations Details 44:12
Lewis and Randall rule partial Molar Properties Details 49:11
Partial Molar Property Estimation from Mixing Experiments Details 49:53
Partial Molar Property Estimation (cont.,) Excess Property Details 50:8
Activity Coefficient from Excess Property Details 50:13
Activity Coefficient from Excess Property (cont.,) Details 49:35
Activity Coefficient from Excess Pro.,Models for Activity Coefficient in Binary Sys.. Details 50:30
Models for Activity Coefficient in Binary Systems(cont.,) Details 47:56
Review of Module 4 Details 40:13
Criteria for Phase Equilibrium Phase Rule for Non-reacting Biosystems Details 50:8
Clausius – Clayperon Equation Details 49:12
Clausius – Clayperon Equation(cont.,)vapour-Liquid Equilibrium Details 50:8
Vapour-Liquid Equilibrium.Estimation of Fugacity coefficient … Details 50:18
Liquid/Liquid and Solid/Liquid Equilibria Details 50:9
Review of Module 5 Details 36:36
Criteria for Bio-reaction Equilibria Details 49:55
Phase rule for Reacting Biosystems Equilibrium constants Details 50:30
Effect of Temperature and Pressure on the Equilibrium constants Details 48:17
Reaction in Liquid or Solid Phases Details 49:43
Free energy Changes for some Bioreactions Details 49:23
Electrolytes Details 50:22
Course Review Details 51:23

This course is part of NPTEL online courses, delivered by IIT Madras.

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