INTRODUCTION : Introduction To Organometallic Chemistry;C1 LIGANDS AND SIMPLE REACTIONS : Metal carbonyl complexes – Metal carbonyls –Part II – Ligand substitution reactions – Substitutes for carbonyl ligands – Carbene complexes – Carbene complexes continued – Non-Carbon Ancillary ligands – Non-Carbon Ancillary ligands continued – Metal alkyl complexes – Ligand Insertion Reactions – ηm (m=even) ligands : Metal alkene complexes – Alkynes η2 bonding – Metal dihydrogen and hydrides – Migratory Insertion reaction with alkynes – ηm (m=4 dienes and m=2n, polyenes) – Reactions with oxidation state change : Oxidative addition & Vaskas complex mechanism – Reductive elimination – Reductive Elimination mechanism – Oxidative coupling with C-C bond formation – Metathesis reactions – ηm (m=odd) ligands : Metal-allyls – η3 complexes-synthesis, bonding – Metal-allyls – η3 complexes-fluxionality, reactivity – C-C single bond forming reactions – Metallocenes : η5 Cyclopentadienyl – complexes – η6 arene Metal complexes – Half sandwich complexes – Reactivity changes in coordinated ligands – Dynamics and structures of organometallic compounds : The isolobal analogy – Fluxional Properties of Organometallics – Quantifying Steric and electronic factors – Useful catalytic and Stoichiometric reactions : Hydrogenation reactions – Addition of HX to olefins – Reactions with CO insertion – Organometallics promoted C-X coupling – Organometallic polymerization – C-H activation – Applications of organometallic chemistry : Asymmetric Catalysis – Medicinal applications of organometallic complexes – Special Properties and Applications

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Course Curriculum

Introduction to Organometallic chemistry Details 58:53
Metal carbonyls –Part II Details 58:45
Ligand substitution reactions Details
Substitutes for carbonyl ligands Details
Carbene complexes Details 58:18
Carbene complexes continued I Details 57:24
Non-Carbon Ancillary ligands Details 55:40
Non-Carbon Ancillary ligands continued I Details 58:40
Metal alkyl complexes Details 55:50
Ligand Insertion Reactions Details 57:52
Metal alkene complexes Details 56:51
Alkynes η2 bonding Details 57:9
Metal dihydrogen and hydrides Details 59:9
Migratory Insertion reaction with alkynes Details 53:45
ηm (m=4 dienes and m=2n,polyenes) Details 56:24
Oxidative addition & Vaskas complex mechanism Details 58:36
Reductive elimination Details 47:10
Reductive Elimination mechanism Details 58:38
Oxidative coupling with C-C bond formation Details 54:15
Metathesis reactions Details 52:29
Metal-allyls – η 3 complexes-synthesis, bonding Details 58:36
Metal-allyls – η 3 complexes-fluxionality, reactivity I Details 58:34
C-C single bond forming reactions Details 53:54
η 5 Cyclopentadienyl – complexes Details 1:3:13
η6 arene Metal complexes Details 56:24
Half sandwich complexes Details 57:32
Reactivity changes in coordinated ligands Details 55:18
The isolobal analogy Details 58:25
Fluxional Properties of Organometallics Details 56:56
Quantifying Steric and electronic factors Details 52:12
Hydrogenation reactions Details 28:4
Addition of HX to olefins Details 55:55
Organometallic polymerization Details 53:10
C-H activation Details 56:27
Asymmetric Catalysis Details 0:55
Medicinal applications of organometallic complexes Details 54:32
Special Properties and Applications Details 1:1:56
Metal carbonyl complexes Details 58:7
Organometallics promoted C-X coupling Details
Addition of HX to olefins Details 55:55

This Course is provided by IISc Bangalore as part of NPTEL online courses.

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